{"paper":{"title":"Formation of single-phase disordered CsxFe2-ySe2 at high pressure","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.supr-con","authors_text":"A. Krzton-Maziopa, E. Pomjakushina, K. Conder, M. Mezouar, V. Svitlyk","submitted_at":"2017-12-06T15:51:19Z","abstract_excerpt":"A single-phase high pressure (HP) modification of CsxFe2-ySe2 was synthesized at 11.8 GPa at ambient temperature. Structurally this polymorph is similar to the minor low pressure (LP) superconducting phase, namely they both crystallize in a ThCr2Si2-type structure without ordering of the Fe vacancies within the Fe-deficient FeSe4 layers. The HP CsxFe2-ySe2 polymorph is found to be less crystalline and nearly twice as soft compared to the parent major and minor phases of CsxFe2-ySe2. It can be quenched to low pressures and is stable at least on the scale of weeks. At ambient pressure the HP pol"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1712.02244","kind":"arxiv","version":2},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}