{"paper":{"title":"Blackbody radiation and thermal effects on chemical reactions and phase transitions in cavities","license":"http://creativecommons.org/licenses/by/4.0/","headline":"","cross_cats":[],"primary_cat":"physics.chem-ph","authors_text":"Joel Yuen-Zhou, Sindhana Pannir-Sivajothi","submitted_at":"2024-02-01T22:13:25Z","abstract_excerpt":"An important question in polariton chemistry is whether reacting molecules are in thermal equilibrium with their surroundings. If not, can experimental changes observed in reaction rates of molecules in a cavity (even without optical pumping) be attributed to a higher/lower temperature inside the cavity? In this work, we address this question by computing temperature differences between reacting molecules inside a cavity and the air outside. We find this temperature difference to be negligible for most reactions. On the other hand, for phase transitions inside cavities, as the temperature of t"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2402.01043","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2402.01043/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}