{"paper":{"title":"Ambiguity in B-Site cation ordering: A Case study of the double perovskite Ca$_2$CoNbO$_6$","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Alexandr I. Balitskiy, Dina I. Fazlizhanova, Ivan V. Yatsyk, Rushana M. Eremina, Ruslan G. Batulin, Svetlana A. Artiukova, Tatiana I. Chupakhina, Vladislav V. Bazhal, Yulia A. Deeva","submitted_at":"2026-05-22T12:23:20Z","abstract_excerpt":"The ordering of cations in the B sublattice remains a challenging issue in double perovskites. In this work, a combined experimental and theoretical approach was employed to investigate the Co/Nb distribution in Ca$_2$CoNbO$_6$ and its influence on magnetic and transport properties. The density functional theory, supported by magnetic susceptibility measurements, indicates that Co adopts a high-spin Co$^{3+}$ state. No long-range magnetic ordering was observed down to low temperatures; however, the presence of short-range correlations points to the partial disorder in the Co/Nb sublattice. Thi"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2605.23558","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2605.23558/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}