{"paper":{"title":"Elucidating the Control of Circular Dichroism in Ion Yield via Chirped Pulses with Purposeful Models","license":"http://creativecommons.org/licenses/by-nc-sa/4.0/","headline":"","cross_cats":["physics.chem-ph","quant-ph"],"primary_cat":"physics.atom-ph","authors_text":"Daniel M. Reich, Leon A. Kerber","submitted_at":"2026-06-05T13:44:21Z","abstract_excerpt":"We theoretically investigate circular dichroism in the ion yield following $1+1+1$ ionization of 3-methylcyclopentanone using femtosecond linearly chirped laser pulses, inspired by recent experiments by Das et al. [Phys. Chem. Chem. Phys. 27, 8043 (2025)]. To this end, we numerically solve the time-dependent Schr\\\"odinger equation and evaluate the total population in the Rydberg states at the end of the second absorption step. The A-band transition in the first absorption step is treated using state-of-the-art quantum-chemical calculations, whereas the second absorption step is described via a"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2606.07269","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2606.07269/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}