{"paper":{"title":"Brownmillerite Ca2Co2O5: Synthesis, Stability, and Re-entrant Single-Crystal-to-Single-Crystal Structural Transitions","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Christos D. Malliakas, Hong Zheng, Jared M. Allred, J.F. Mitchell, Junjie Zhang, Qingan Li, Tian-Heng Han, Yang Ren","submitted_at":"2014-11-20T17:34:08Z","abstract_excerpt":"Ca2Co2O5 in the brownmillerite form was synthesized using a high-pressure optical-image floating zone furnace, and single crystals with dimensions up to 1.4x0.8x0.5 mm3 were obtained. At room temperature, Ca2Co2O5 crystallizes as a fully ordered brownmillerite variant in the orthorhombic space group Pcmb (No. 57) with unit cell parameters a=5.28960(10) {\\AA}, b=14.9240(2) {\\AA}, and c=10.9547(2) {\\AA}. With decreasing temperature, it undergoes a re-entrant sequence of first-order structural phase transitions (Pcmb to P2/c11 to P121/m1 to Pcmb) that is unprecedented among brownmillerites, broad"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1411.5615","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}