{"paper":{"title":"Roaming dynamics in Ketene isomerization","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["cond-mat.stat-mech","math.DS","nlin.CD"],"primary_cat":"physics.chem-ph","authors_text":"Fr\\'ed\\'eric A. L. Maugui\\`ere, Gregory S. Ezra, Peter Collins, Stavros C. Farantos, Stephen Wiggins","submitted_at":"2014-03-25T22:00:36Z","abstract_excerpt":"A reduced two dimensional model is used to study Ketene isomerization reaction. In light of recent results by Ulusoy \\textit{et al.} [J.\\ Phys.\\ Chem.\\ A {\\bf 117}, 7553 (2013)], the present work focuses on the generalization of the roaming mechanism to the Ketene isomerization reaction by applying our phase space approach previously used to elucidate the roaming phenomenon in ion-molecule reactions. Roaming is again found be associated with the trapping of trajectories in a phase space region between two dividing surfaces; trajectories are classified as reactive or nonreactive, and are furthe"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1403.6520","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}