{"paper":{"title":"An in- and ex-situ TEM study into the oxidisation of titanium (IV) sulphide","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Clive Downing, Clotilde S. Cucinotta, Edmund Long, Edward A. Lewis, Eric Prestat, Sarah J. Haigh, Sean O'Brien, Stefano Sanvito, Valeria Nicolosi","submitted_at":"2015-05-29T14:57:57Z","abstract_excerpt":"The degradation of liquid dispersed titanium (IV) sulphide (TiS$_2$) is studied from the point of view of oxidisation. TiS$_2$ is a layered two-dimensional nanomaterial, with potential for energy storage applications. However, flakes in dispersion were observed to degrade. We examined two oxidisation routes: deionised water at room temperature and oxygen gas within the temperature range 150-350{\\deg}C. Water was seen to slowly oxidise flakes inwards from the edge, forming an amorphous oxide, a result comparable to the state of flakes which degraded within the original dispersion. Oxygen gas wa"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1505.08074","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}