{"paper":{"title":"Correlating parent-fragment relationships in cluster photoionization","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"physics.atm-clus","authors_text":"Beg\\\"um Rukiye \\\"Ozer, In Heo, Jong Chan Lee, Thomas Schultz","submitted_at":"2024-02-13T11:58:02Z","abstract_excerpt":"Fragment signals in ordinary mass spectra carry no label to identify their parent molecule. By correlating mass signals with rotational Raman spectra, we created a method to label each ion signal with the spectroscopic fingerprint of its neutral parent molecule. In data for a carbon disulfide molecular cluster beam, we assigned 28 distinct ionization and fragmentation channels based on their mass-correlated rotational fingerprints. Unexpected observations included the formation of energetic S2 and SCCS cationic fragments from the CS2-dimer cluster and a significant CS3 signal, uncorrelated to "},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2402.08398","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2402.08398/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}