{"paper":{"title":"Solving the \"Magic Angle\" Challenge in Determining Molecular Orientation at Interfaces","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"physics.chem-ph","authors_text":"Jiaxi Wang, Wei Xiong, Yingmin Li, Zhiguo Li","submitted_at":"2016-03-08T23:38:54Z","abstract_excerpt":"We introduce a novel method to determine the orientation heterogeneity (mean tilt angle and orientational distribution) of molecules at interfaces using heterodyne two-dimensional sum frequency generation spectroscopy. By doing so, we not only have solved the long-standing \"magic angle\" challenge, i.e. the measurement of molecular orientation by assuming a narrow orientational distribution results in ambiguities, but we also are able to determine the orientational distribution, which is otherwise difficult to measure. We applied our new method to a CO2 reduction catalyst/gold interface and fou"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1603.02739","kind":"arxiv","version":2},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}