{"paper":{"title":"A Theoretical Framework for the Coupling of Macroscale-Nanoscale Mechanochemical Phenomena in Condensed Matter","license":"http://creativecommons.org/licenses/by/4.0/","headline":"","cross_cats":["cond-mat.mtrl-sci","physics.chem-ph"],"primary_cat":"cond-mat.soft","authors_text":"Brenden W Hamilton","submitted_at":"2026-07-22T14:36:13Z","abstract_excerpt":"The field of covalent mechanochemistry has transitioned from fundamental science to engineering applications, yet it lacks a robust theoretical framework for predicting reaction kinetics in condensed matter. Existing analytical models fail under realistic conditions where macroscopic strains drive molecular-scale deformations that are highly non-linear. We develop a non-perturbative theoretical framework that captures activation barrier changes in highly strained molecules undergoing complex, non-linear deformations, describing the macroscale-nanoscale coupling of phenomena. The framework yiel"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2607.20217","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2607.20217/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}