{"paper":{"title":"NMR detection of dynamical processes in antiferroelectric nanoclusters during the order-disorder transition in NH4H2AsO4","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mes-hall","authors_text":"I. Chiorescu, N.S. Dalal, O. Gunaydin-Sen, R. Fu","submitted_at":"2015-04-23T11:07:20Z","abstract_excerpt":"We study the dynamics of inorganic antiferroelectric nanoclusters formed during an order-disorder transition and demonstrate the coexistence of the two phases in a region of 2-3 K around the transition temperature TN~215 K. Single crystals of NH4H2AsO4, a model hydrogen-bonded compound, show an antiferroelectric-paraelectric transition studied by means of highly sensitive magic angle spinning 15N NMR at 21.1 T. The phase co-existence is demonstrated by a double-peak structure of the chemical shift. Two-dimensional chemical exchange spectroscopy and spin-lattice relaxation time (T1) measurement"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1504.06124","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}