{"paper":{"title":"Using excited states and degeneracies to enhance the electric polarizability and first hyperpolarizability","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["quant-ph"],"primary_cat":"physics.optics","authors_text":"Ethan Crowell, Mark Kuzyk","submitted_at":"2018-05-17T21:57:40Z","abstract_excerpt":"We investigate the efficacy of boosting the nonlinear-optical response by using novel systems such as those in an excited state or with a degenerate ground state. By applying the Three Level Ansatz (TLA) and using the Thomas-Reiche-Kuhn (TRK) sum rules as constraints, we find the electric polarizability and first hyperpolarizability of excited state systems to be bounded, but larger than those derived for a system in the ground state. It is shown that a system with a degenerate ground state can have divergent intrinsic polarizabilities and that such divergences are real and not relics of a pat"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1805.06977","kind":"arxiv","version":2},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}