{"paper":{"title":"Energy and radiative properties of the (3)1{\\Pi} and (5)1{\\Sigma}+ states of RbCs: Experiment and theory","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["physics.chem-ph"],"primary_cat":"physics.atom-ph","authors_text":"A. Kruzins, A. V. Stolyarov, E. A. Pazyuk, K. Alps, M. Tamanis, O. Nikolayeva, R. Ferber","submitted_at":"2019-05-21T13:09:24Z","abstract_excerpt":"We combined high-resolution Fourier-transform spectroscopy and large-scale electronic structure calculation to study energy and radiative properties of the high-lying (3)1{\\Pi} and (5)1{\\Sigma}+ states of the RbCs molecule. The laser-induced (5)1{\\Sigma}+(4)1{\\Sigma}+(3)1{\\Pi}-A(2)1{\\Sigma}+ b(1)3{\\Pi} fluorescence (LIF) spectra were recorded by the Bruker IFS-125(HR) spectrometer in the frequency range {\\nu} 5500 to 10000cm-1 with the instrumental resolution of 0.03 cm-1. The rotational assignment of the observed LIF progressions, which exhibit irregular vibrational-rotational spacing due to "},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1905.08599","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}