{"paper":{"title":"Polymer-Regulated Freezing of Water Droplets Revealed by Synchrotron X-ray Imaging and Raman Spectroscopy","license":"http://creativecommons.org/licenses/by/4.0/","headline":"","cross_cats":["physics.flu-dyn"],"primary_cat":"cond-mat.soft","authors_text":"Bomi Kim, Hyeonjun An, Jae-Hong Lim, Jae Kwan Im, Joonwoo Jeong, Kitae Kim, Min Woo Kim, Seob-Gu Kim","submitted_at":"2026-05-31T14:10:35Z","abstract_excerpt":"Adding a polymer to a sessile water droplet not only lowers its freezing point but also suppresses the tip singularity that forms during its freezing on cold substrates. Here, we employ synchrotron X-ray and Raman imaging to elucidate the spatiotemporal mechanism underlying tip suppression in an aqueous polyvinyl alcohol (PVA) solution, a model polymer solution. As the polymer concentration increases, we observe slower propagation of the freezing front, reduced bubble entrapment, and a progressively more rounded apex across the volumes and molecular weights examined. X-ray tomography reveals t"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2606.01251","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2606.01251/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}