{"paper":{"title":"Observation of vacancy-related polaron states at the surface of anatase and rutile TiO2 by high-resolution photoelectron spectroscopy","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Andrew G. Thomas, Anna Levy, Balasubramanian Thiagarajan, Johan Adell, Karen L. Syres, Mark J. Jackmana, Peter De\\'ak","submitted_at":"2014-06-12T22:38:33Z","abstract_excerpt":"Defects in the surface region of a reducible oxide, as TiO2, have a profound effect on applications, while their nature is very much influenced by the possibility of small polaron formation. Here, we probe rutile (110) and anatase (101) single crystals via high-resolution ultraviolet photoelectron spectroscopy and resolve multiple components of the well-known defect state in the band gap. In rutile, we find two at VBM+2.1 eV and VBM+1.4 eV, which we assign to subsurface polaron traps and vacancy-bound states, respectively, confirming the predicted partial suppression of polaron formation at hi"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1406.3385","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}