{"paper":{"title":"A facile route to synthesize cubic gauche polymeric nitrogen","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["cond-mat.supr-con","physics.chem-ph"],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Changqing Jin, Chuan Xiao, Jianfa Zhao, Jun Zhang, Ke Lu, Ruibin Liu, Runteng Chen, Shaomin Feng, XiaoDong Liu, Yi Peng, Zelong Wang","submitted_at":"2024-11-15T16:30:46Z","abstract_excerpt":"In this work, the long-sought cg-N with N-N single bond has been synthesized for the first time by a thermal-driven-only chemical route at ambient conditions. The successful synthesis of cg-N was achieved by first creating a solution of azides, which was then pretreated under vacuum conditions. Following the pretreatment, the resultant concentrated azide was heated at temperatures ranging from 260{\\deg}C to 330{\\deg}C for a reaction time of 3 hours, ultimately leading to the formation of cg-N. The emergent intense Raman peak characterized of cg-N provides solid evidence that the double bonded "},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2411.10331","kind":"arxiv","version":3},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2411.10331/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}