{"paper":{"title":"Dynamics of monohydroxy alcohols with chain-like structures: Hydrogen bonding lifetime, chain swapping, and Debye process","license":"http://creativecommons.org/licenses/by/4.0/","headline":"","cross_cats":["physics.chem-ph"],"primary_cat":"cond-mat.soft","authors_text":"Shalin Patil, Shiwang Cheng","submitted_at":"2026-06-17T02:47:20Z","abstract_excerpt":"By assuming reversible H-bonding association and dissociation, this work provides a description of the supramolecular structure and dynamics of monohydroxy alcohols (MAs) within the framework of a recently proposed living chain model (LCM). Structurally, reversible H-bonding leads to a single exponential distribution of the molar concentration of the supramolecular chain with length N. Dynamically, reversible H-bonding enables supramolecular chain breakage and recombination, which modifies the relaxation time of the supramolecular chains. In addition to the structural relaxation, tau_a, and th"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2606.18626","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2606.18626/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}