{"paper":{"title":"Ca-bearing cyanopolyynes in IRC+10216","license":"http://creativecommons.org/licenses/by/4.0/","headline":"","cross_cats":["astro-ph.GA"],"primary_cat":"astro-ph.SR","authors_text":"T. J. Millar","submitted_at":"2026-05-30T09:06:59Z","abstract_excerpt":"In recent years, a number of metal-containing, carbon-chain species have been detected in the external circumstellar envelope of the carbon-rich AGB star IRC+10216. The most common metal detected in such species is Mg, for which molecules as large as MgC$_5$N, MgC$_5$N$^+$ MgC$_6$H and MgC$_6$H$^+$ have been observed. In this paper, we calculate the likely abundances of the Ca-bearing cyanopolyynes, CaC$_{2n+1}$N for n = 1-4, drawing the conclusion that the observed abundance of CaNC must be made from much larger Ca-terminated cyanopolyyne ions, which requires considerable rearrangement in the"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2606.00631","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2606.00631/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}