{"paper":{"title":"Comparative Investigation of the High Pressure Autoignition of the Butanol Isomers","license":"http://creativecommons.org/licenses/by/4.0/","headline":"","cross_cats":[],"primary_cat":"physics.chem-ph","authors_text":"Bryan W. Weber, Chih-Jen Sung","submitted_at":"2017-06-06T16:19:39Z","abstract_excerpt":"Investigation of the autoignition delay of the butanol isomers has been performed at elevated pressures of 15 bar and 30 bar and low to intermediate temperatures of 680-860 K. The reactivity of the stoichiometric isomers of butanol, in terms of inverse ignition delay, was ranked as n-butanol > sec-butanol ~ iso-butanol > tert-butanol at a compressed pressure of 15 bar but changed to n-butanol > tert-butanol > sec-butanol > iso-butanol at 30 bar. For the temperature and pressure conditions in this study, no NTC or two-stage ignition behavior were observed. However, for both of the compressed pr"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1706.01842","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}