{"paper":{"title":"A Metastable CaSH$_3$ Phase Composed of HS Honeycomb Sheets that is Superconducting Under Pressure","license":"http://creativecommons.org/licenses/by/4.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.supr-con","authors_text":"Eva Zurek, Nisha Geng, Tiange Bi, Xiaoyu Wang, Yan Yan","submitted_at":"2020-12-30T00:28:26Z","abstract_excerpt":"Evolutionary searches predicted a number of ternary phases that could be synthesized at pressures of 100-300~GPa. $P6_3/mmc$ CaSH$_2$, $Pnma$ CaSH$_2$, $Cmc2_1$ CaSH$_6$, and $I\\bar{4}$ CaSH$_{20}$ were composed of a Ca-S lattice along with H$_2$ molecules coordinated in a ``side-on'' fashion to Ca. The H-H bond lengths in these semiconducting phases were elongated because of H$_2$ $\\sigma\\rightarrow$ Ca d donation, and Ca d$\\rightarrow$ H$_2$ $\\sigma^*$ back-donation, via a Kubas-like mechanism. $P\\bar{6}m2$ CaSH$_3$, consisting of two-dimensional HS and CaH$_2$ sheets, was metastable and met"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2012.14985","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2012.14985/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}