{"paper":{"title":"Ionization energies for Rydberg $^4 \\mathrm{He}$ ($1snp\\,^{1,3}P$) states using the correlated B-spline basis function method","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"physics.atom-ph","authors_text":"Hao Fang, Jing Chi, Li-Yan Tang, Ting-Yun Shi, Yong-Hui Zhang","submitted_at":"2026-06-03T11:50:49Z","abstract_excerpt":"We extend the correlated B-spline basis function (C-BSBF) method to high-precision calculations of the ionization energies of helium Rydberg $n^{1,3}P$ states ($n=24$--$35$). Using a unified basis set, we evaluate nonrelativistic energies, relativistic corrections of order $m\\alpha^4$ (including finite-mass recoil), QED contributions of order $m\\alpha^5$, and partial $m\\alpha^6$ terms (singlet-triplet mixing, one- and two-loop radiative corrections). The remaining higher-order contributions are estimated via $1/n^3$ scaling. The resulting ionization energies achieve kHz-level accuracy and are "},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2606.04768","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2606.04768/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}