{"paper":{"title":"Grain Surface Reactions in Molecular Clouds: The Effect of Cosmic Rays and Quantum Tunneling","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"astro-ph.GA","authors_text":"Franck Hersant, Laura Reboussin, St\\'ephane Guilloteau, Valentine Wakelam","submitted_at":"2014-03-20T16:21:50Z","abstract_excerpt":"Grain-surface reactions play an essential role in interstellar chemistry, since dust grain catalyses reactions at its surface allowing for the formation of molecules. We used a chemical model in which both gas-phase and grain-surface reactions occur and studied particularly the diffusion mechanisms on the surface of the grains. Surface reactions can occur via thermal hopping when species cross over a potential barrier or via quantum tunneling when species cross through this barrier. We show that the thermal diffusion (hopping) can be much more efficient after a cosmic ray particle collides wit"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1403.5189","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}