{"paper":{"title":"Stark Field Modulated Microwave Detection of Molecular Chirality","license":"http://creativecommons.org/licenses/by/3.0/","headline":"","cross_cats":["physics.atom-ph"],"primary_cat":"physics.chem-ph","authors_text":"Kevin K. Lehmann","submitted_at":"2015-01-30T18:36:49Z","abstract_excerpt":"Patterson, Schnell, \\& Doyle, {\\it Nature} {\\bf 497}, 475 (2013) introduced a microwave experiment that produces a perpendicularly polarized molecular emission when chiral molecules are resonantly excited in the presence of a Stark Field that is then adiabatically switched off before observation of the emission. The sign of the signal is opposite for two stereo-enantiomers and thus the magnitude of the signal gives the enantiomeric excess of the sample. This paper presents a detailed presentation of the theory behind this and provides expressions for the absolute calculation of the expected si"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1501.07874","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}