{"paper":{"title":"XANES spectroscopy study of Pb(Ti, Zr)O3 ferroelectric thin films","license":"","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Marija Kosec, Mira Mandeljc, N.V. Bausk, S. B. Erenburg, S.G. Kozlova, S.P. Gabuda","submitted_at":"2003-12-21T15:35:34Z","abstract_excerpt":"Thin films of zirconium-rich perovskites Pb1-3x/2 Lax Zr0.65 Ti0.35O3 (PLZT; x=0.095) were studied using X-ray absorption near-edge structure (XANES) spectroscopy. Is shown, that slow crystallization of the system is accompanied by partial reduction of lead oxides to a metal (Pb0) state. The same results were found in the samples of the same composition with addition of 30% mol of PbO. The evidence for stereo active 6s2 lone-pair is discussed."},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"cond-mat/0312559","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/cond-mat/0312559/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}