{"paper":{"title":"Triplet-Polaron Interaction Induced Upconversion from Triplet to Singlet: a New Way to Obtain Highly Efficient OLEDs","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"physics.chem-ph","authors_text":"Ablikim Obolda, Chuanyou He, Feng Li, Hongwei Ma, Jiajun Ren, Qiming Peng, Tian Zhang, Zhigang Shuai","submitted_at":"2015-09-24T03:28:56Z","abstract_excerpt":"The triplet harvesting is a main challenge in organic light-emitting devices (OLEDs), due to the radiative decay of triplet is spin-forbidden. Here, we designed and synthesized two D-A type molecules, TPA-TAZ and TCP. The OLEDs based on them exhibit deep-blue emission and the singlet formation ratios are higher than the simple spin-statistics of 25 %. Specially, a TPA-TAZ-based OLED achieves a maximum EQE of 6.8 %, which is the largest value of the undoped OLEDs with CIE(y)< 0.06 (the EBU blue standard) up to date. Comprehensive experiments eliminate the triplet-harvesting processes of thermal"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1509.07224","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}