{"paper":{"title":"New mechanism for non-trivial intra-molecular vibrational dynamics","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mes-hall","authors_text":"Chernogolovka, E. I. Kats (Laue-Langevin Institute, France, Grenoble, L. D. Landau Institute for Theoretical Physics, Moscow, RAS, Russia), V.A.Benderskii (Institute of Chemical Physics Problems","submitted_at":"2009-05-28T12:16:08Z","abstract_excerpt":"We investigate the time evolution process of one selected (initially prepared by optical pumping) vibrational molecular state, coupled to all other intra-molecular vibrational states of the same molecule, and also to its environment. Molecular states forming the first reservoir are characterised by a discrete dense spectrum, whereas the environment reservoir states form a continuous spectrum. Assuming the equidistant reservoir states we find the exact analytical solution of the quantum dynamic equations. System reservoirs couplings yield to spontaneous decay of the states, whereas system-reser"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"0905.4628","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}