{"paper":{"title":"$S$ = 1/2 ferromagnetic-antiferromagnetic alternating Heisenberg chain in a zinc-verdazyl complex","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.str-el","authors_text":"Hironori Yamaguchi, Kenji Iwase, Shunichiro Kittaka, Tokuro Shimokawa, Toshio Ono, Toshiro Sakakibara, Yasuhiro Shinpuku, Yohei Kono, Yuko Hosokoshi","submitted_at":"2015-02-24T13:32:21Z","abstract_excerpt":"We successfully synthesized the zinc-verdazyl complex [Zn(hfac)$_2$]$\\cdot$($o$-Py-V) [hfac = 1,1,1,5,5,5-hexafluoroacetylacetonate; $o$-Py-V = 3-(2-pyridyl)-1,5-diphenylverdazyl], which is an ideal model compound with an $S$ = 1/2 ferromagnetic-antiferromagnetic alternating Heisenberg chain (F-AF AHC). $Ab$ $initio$ molecular orbital (MO) calculations indicate that two dominant interactions $J_{\\rm{F}}$ and $J_{\\rm{AF}}$ form the $S=1/2$ F-AF AHC in this compound. The magnetic susceptibility and magnetic specific heat of the compound exhibit thermally activated behavior below approximately 1 "},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1502.06804","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}