{"paper":{"title":"Precision measurement of the last bound states in H$_2$ and determination of the H + H scattering length","license":"http://creativecommons.org/licenses/by/4.0/","headline":"","cross_cats":["physics.chem-ph"],"primary_cat":"physics.atom-ph","authors_text":"K.-F. Lai, M. Beyer, W. Ubachs","submitted_at":"2025-02-03T23:09:15Z","abstract_excerpt":"The binding energies of the five bound rotational levels $J=0-4$ in the highest vibrational level $v=14$ in the X$^1\\Sigma_g^+$ ground electronic state of H$_2$ were measured in a three-step ultraviolet-laser experiment. Two-photon UV-photolysis of H$_2$S produced population in these high-lying bound states, that were subsequently interrogated at high precision via Doppler-free spectroscopy of the F$^1\\Sigma_g^+$ - X$^1\\Sigma_g^+$ system. A third UV-laser was used for detection through auto-ionizing resonances. The experimentally determined binding energies were found to be in excellent agreem"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2502.01877","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2502.01877/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}