{"paper":{"title":"Triangulene-based diradicals as a blueprint for molecular quantum platforms with optical addressability and long spin coherence times","license":"http://creativecommons.org/licenses/by/4.0/","headline":"","cross_cats":["cond-mat.mtrl-sci"],"primary_cat":"quant-ph","authors_text":"Alessandro Lunghi, Arup Sarkar, Cathal Hogan, Conor Ryan, Lorenzo A. Mariano","submitted_at":"2026-07-09T16:04:38Z","abstract_excerpt":"The identification of molecules that combine long spin coherence times and efficient spin-optical interfaces, ideally at room temperature, is pivotal towards the development of molecular quantum technology. By means of advanced first-principles methods, we here unravel the electronic structure for triangulene (1), its aza-cation derivative (2), and the crystal of 2,6,10-tri-tert-butyl-4,8,12-trimesityl-triangulene (3), and show that these organic diradicals possess a triplet ground state well separated from the first singlet excited state approaching 0.5 eV, closely resembling solid-state defe"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2607.08634","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2607.08634/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}