{"paper":{"title":"Chiral Pt(Me-BPCH): Synthesis and theoretical investigation of parity violation sensitivity","license":"http://creativecommons.org/licenses/by-nc-nd/4.0/","headline":"","cross_cats":[],"primary_cat":"physics.chem-ph","authors_text":"Anastasia Borschevsky, Beno\\^it Darqui\\'e, Charles Silva, D. Scott Bohle, Eduardus, J. Wietze J. van Boven, Luk\\'a\\v{s} F. Pa\\v{s}teka, Philip Karageorghis","submitted_at":"2025-09-30T15:36:16Z","abstract_excerpt":"A complex of platinum and the tetra-coordinate chelating ligand, R,R'-6,6'-dimethyl-N,N'-bis(2'-pyridine-carboxamide)-1-cyclohexane (Me-BPCH) is investigated as a potential candidate for measurement of parity violation (PV) in chiral molecules. The synthesis of Pt(Me-BPCH) is presented alongside computational investigation of PV sensitivity in its vibrational spectrum. Pt(Me-BPCH) is compared to other two derivatives of this complex, Au(Me-BPCH) and Pt(CF$_3$-BPCH) in terms of their PV response and suitability for measurement. We identify the most promising vibrational transitions based on the"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2509.26407","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2509.26407/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}