{"paper":{"title":"Numerical analysis of XMCD sum rules at the $L$-edge: when do they fail?","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"C. von Korff Schmising, J. K. Dewhurst, P. Elliott, S. Eisebitt, S. Shallcross, S. Sharma","submitted_at":"2021-04-02T13:20:17Z","abstract_excerpt":"In the highly non-equilibrium conditions of laser induced spin dynamics magnetic moments can only be obtained from the spectral information, most commonly from the spectroscopy of semi-core states using the so-called x-ray magnetic circular dichroism (XMCD) sum rules. The validity of the these sum rules in tracking femtosecond spin dynamics remains, however, an open question. Employing the time dependent extension of density functional theory (TD-DFT) we compare spectroscopically obtained moments with those directly calculated from the TD-DFT densities. We find that for experimentally typical "},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2104.01039","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2104.01039/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}