{"paper":{"title":"Magic angle effects in a trigonal Mn(III)3 cluster: deconstruction of a single-molecule magnet","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"En-Che Yang, Jonathan Marbey, Pei-Rung Gan, Stephen Hill","submitted_at":"2018-08-27T16:52:55Z","abstract_excerpt":"We present angle-dependent high-frequency EPR studies on a single-crystal of a trigonal Mn3 cluster with an unusual structure in which the local magnetic easy-axes of the constituent Mn(III) ions are tilted significantly away from the molecular C3 axis towards the magic-angle of 54.7 degrees, resulting in an almost complete cancelation of the 2nd-order axial magnetic anisotropy associated with the ferromagnetically coupled total spin ST = 6 ground state. This contrasts the situation in many related Mn3 single-molecule magnets (SMMs) that have been studied intensively in the past, for which the"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1808.08922","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}