{"paper":{"title":"FTIR and GCMS analysis of epoxy resin decomposition products feeding the flame during UL 94 standard flammability test. Application to the understanding of the blowing-out effect in epoxy/polyhedral silsesquioxane formulations","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"physics.chem-ph","authors_text":"Alberto Fina, Giuseppe Ferraro, Rongjie Yang, Wenchao Zhang","submitted_at":"2018-06-11T22:14:20Z","abstract_excerpt":"A novel method was developed for the sampling of volatiles produces by polymer decomposition during UL94 standard flammability tests, allowing to collect, separate and analyze the precise composition of the fuel mixture feeding the flame in the real flammability tests. The system was validated on epoxy resin/polyhedral oligomeric silsesquioxanes and found extremely informative for the understanding of the flame retardancy mechanisms of POSS, previously referred to as the blowing-out effect. Collected products were analyzed by infrared spectroscopy and gas chromatography/mass spectroscopy, to i"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1806.10921","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}