{"paper":{"title":"Manganese valence and magnetotransport in ultrathin films of La$_{0.67}$Ca$_{0.33}$MnO$_3$","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mes-hall","authors_text":"C. Beekman, H. Zandbergen, J. Aarts, M. Porcu","submitted_at":"2011-02-19T16:57:46Z","abstract_excerpt":"We report a comparative study of the properties of very thin films of La$_{0.67}$Ca$_{0.33}$MnO$_3$ grown epitaxially under strain on flat SrTiO$_3$ (STO), lattice matched on NdGaO$_3$ (NGO), and strained on $1^{\\circ}$-miscut STO. We use transmission electron microscopy and electron energy loss spectroscopy to study the microstructure, composition, and Mn valence state. Near the interface we find no significant segregation, but a charge compensation layer where the valence is enhanced over the nominal value of 3.3+, and a relaxation to this value over several nanometer. The transport properti"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1102.4004","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}