{"paper":{"title":"Characterization of the electronic ground state of He$_2^+$ by high-resolution photoelectron spectroscopy","license":"http://creativecommons.org/licenses/by/4.0/","headline":"","cross_cats":["physics.chem-ph"],"primary_cat":"physics.atom-ph","authors_text":"F. Merkt, M. Beyer, M. Holdener, N. A. Shahin, V. Wirth","submitted_at":"2025-08-11T14:14:20Z","abstract_excerpt":"Excluding the very shallow potential minimum of the electronic ground state, all bound electronic states of He$_2$ have Rydberg character. Their potential-energy functions are similar to those of the He$_2^+$ states to which the Rydberg series converge. Photoionization and electron-impact ionization of the metastable $a~^3\\Sigma_u^+$ state of He$_2$ are thus characterized by diagonal Franck-Condon factors and only provide access to low vibrational levels of the He$_2^+$ $X^+$ $^2\\Sigma_u^+$ electronic ground state. For this reason, little experimental information is available on the excited vi"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2508.08009","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2508.08009/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}