{"paper":{"title":"Experimental study of the removal of excited state phosphorus atoms by H$_{2}$O and H$_{2}$: implications for the formation of PO in stellar winds","license":"http://creativecommons.org/licenses/by/4.0/","headline":"","cross_cats":["astro-ph.GA"],"primary_cat":"astro-ph.SR","authors_text":"David Gobrecht, John M. C. Plane, Kevin M. Douglas","submitted_at":"2022-06-16T14:08:55Z","abstract_excerpt":"The reactions of the low-lying metastable states of atomic phosphorus, P($^2$D) and P($^2$P), with H$_{2}$O and H$_{2}$ were studied by the pulsed laser photolysis at 248 nm of PCl$_{3}$ , combined with laser induced fluorescence detection of P($^2$D), P($^2$P) and PO. Rate coefficients between 291 and 740 K were measured, along with a yield for the production of PO from P($^2$D or $^2$P) + H$_{2}$O of (35$\\pm$15)%. H$_{2}$ reacts with both excited P states relatively efficiently; physical (i.e. collisional) quenching, rather than chemical reaction to produced PH + H, is shown to be the more l"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2206.08193","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2206.08193/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"}