{"id":"aba18a40-9f86-4804-b8fd-4f3753810de7","arxiv_id":"2412.07204","paper_version":2,"verdict":"CONDITIONAL","confidence":"MODERATE","novelty_score":6.0,"correctness_risk":"medium","formal_verification":"none","parameter_count":9,"one_line_summary":"Full charge-transfer and core-valence exchange effects in an Anderson impurity model reproduce the XMCD and RIXS-MCD subpeak structure of La0.7Sr0.3MnO3 that conventional partial-CT weighted-sum calculations miss.","lead":"The paper builds an Anderson impurity model with full charge transfer and core-valence exchange correlation to reproduce X-ray magnetic circular dichroism and resonant inelastic X-ray scattering spectra of a mixed-valence manganite film. It argues that conventional weighted-sum multiplet calculations miss subpeak features, and that core-valence exchange effects make XMCD sum-rule analyses unreliable in such systems.","discovery_kind":"new_application","skeptic_critique":{"model":"deepseek-v4-flash","headline":"The paper asserts that CVEC invalidates the XMCD sum rules but never tests this claim on its own theoretical spectra; the practical conclusion rests on an undemonstrated non sequitur.","rationale":"The reader's weakest assumption was that the single-site AIM with a static mean-field magnetic field adequately represents metallic LSMO. That is a legitimate general concern about model realism, but it is broad and difficult to settle with one check, and the paper itself already admits the DOS comparison is only qualitative. The more precise and load-bearing weakness, in my reading, is the gap between the spectral-shape argument and the sum-rule conclusion. The central claim as stated has two parts: (i) full CT plus CVEC reproduces the measured XMCD/RIXS-MCD subpeak structure, and (ii) CVEC invalidates standard XMCD sum-rule extraction. Part (i) is supported by the controlled r,s scan in Fig. 2(c), even though parameter fitting and the unfulfilled Jahn-Teller promise (the abstract cites JT distortions that never appear in the Hamiltonian or results) are quality concerns. Part (ii), however, is asserted with no quantitative demonstration. Sum rules are statements about integrals, so the observed sign reversal at the L3 subpeak is suggestive but not sufficient. A reader cannot verify the paper's most practically important takeaway without performing the integration themselves. This is a concrete, addressable omission, not a fatal flaw, and it is independent of the AIM-realism debate: even if the model were the exact Hamiltonian of the material, the paper would still need to show that the sum rules fail. I therefore disagree with the reader's choice of weakest assumption while agreeing with the CONDITIONAL verdict. The condition should be: add the sum-rule test for s=0 versus s=1 in the model, and report the resulting m_orb and m_spin relative to the ground-state moments. This would either substantiate or retract the paper's main 'practical guidance' claim.","tokens_in":21865,"tokens_out":11748,"duration_ms":123150,"concrete_test":"Using the model of Fig. 2 with full CT and the same parameters as Table I, compute the XAS spectra µ+ and µ- for s=0 and s=1. Apply the standard XMCD sum rules: m_orb = -(4/3) * [∫_{L3+L2}(µ+ - µ-) dω] / [∫_{L3+L2}(µ+ + µ-) dω] * n_h, and m_spin from the spin sum rule including the magnetic dipole term ⟨T_z⟩. Compare these with the ground-state expectation values ⟨L_z⟩, ⟨S_z⟩, and ⟨T_z⟩ obtained from the same CI wavefunction. If s=0 reproduces the exact moments and s=1 deviates by more than about 10%, the sum-rule invalidity claim is quantitatively supported; if both are accurate, the claim must be retracted or substantially weakened.","verdict_should_be":"UNCHANGED","load_bearing_attack":"The most consequential claim in the abstract and conclusion is that core-valence exchange correlation (CVEC) makes standard XMCD sum-rule extraction unreliable in light 3d systems. In the XMCD section the text states: 'the conventional analysis on the XMCD sign, hence the sum-rule, is no longer valid in the presence of the CVEC.' This is a non sequitur: the XMCD sum rules are integral relations over the L3 and L2 edges, not pointwise sign analyses. The authors never integrate their computed XMCD spectra using the Thole-Carra formulas, nor do they compare the resulting m_orb and m_spin with the ground-state expectation values of L_z, S_z, and T_z from the same model. Without such a check, the paper's headline practical message is unsupported even within the model itself. This is load-bearing because the reproduction of the subpeak structure is a spectral-shape argument, while the sum-rule claim is a quantitative statement about integrals; a sign-reversed subpeak does not by itself imply that the integrated dichroism fails to encode the moments. If the model's own s=0 and s=1 spectra both satisfy the sum rules to good accuracy, the central narrative about 'profound impact' collapses. Conversely, a demonstration that s=1 breaks the sum rules while s=0 does not would make the paper's strongest claim solid.","agreement_with_reader":"disagree"},"referee_report":{"model":"deepseek-v4-flash","summary":"The paper reports XMCD and RIXS-MCD measurements on a thin film of the mixed-valence ferromagnet La0.7Sr0.3MnO3 and compares them with configuration-interaction Anderson impurity model (AIM) calculations that include full charge-transfer configurations (d3L0 through d10L7) and many-body core-valence exchange correlation (CVEC). The central claim is that only the combination of full CT and CVEC reproduces the experimentally observed subpeak structure, especially the same-sign XMCD features at the L3 and L2 edges, while conventional weighted sums of Mn3+/Mn4+ spectra with or without a single CT state do not. The paper further asserts that CVEC invalidates the standard XMCD sum rules for light 3d transition-metal systems. The theoretical analysis is backed by a controlled scaling scan (r for hopping, s for core-valence Slater parameters) and by a partial-excitation-density decomposition of the final/intermediate states.","tokens_in":22170,"tokens_out":6454,"duration_ms":76995,"significance":"If the central claim is correct, the paper offers a concrete, generalizable recipe for interpreting dichroic soft-x-ray spectra in mixed-valence 3d oxides and provides a cautionary message about sum-rule-based moment extraction. The strengths are the controlled r/s parameter scan, which cleanly isolates the CT and CVEC effects within the model, and the detailed PED analysis that connects spectral features to specific multiplet configurations. The experimental RIXS-MCD map obtained with a TES spectrometer is a valuable dataset in its own right. However, the most consequential practical conclusion, that CVEC invalidates the XMCD sum rules, is asserted rather than demonstrated; the manuscript needs an explicit numerical test before that conclusion can be accepted.","major_comments":[{"comment":"The statement that CVEC invalidates the XMCD sum rules is a load-bearing non sequitur. The text says 'the conventional analysis on the XMCD sign, hence the sum-rule, is no longer valid in the presence of the CVEC,' but the Thole-Carra sum rules are integral relations over the L3 and L2 edges, not pointwise sign analyses. The paper never integrates the calculated XMCD spectra over the L3/L2 ranges, nor does it compare the resulting m_orb and m_spin with the exact ground-state expectation values of L_z, S_z, and T_z from the same AIM. A sign-reversed subpeak does not by itself imply that the integrated dichroism fails to encode the moments. The authors should apply the standard sum-rule formulas to their s=0 and s=1 theoretical spectra and compare with the model's ground-state moments; if the integral relations survive, the central practical conclusion must be withdrawn or sharply qualified.","section":"XMCD SPECTRA (Fig. 2; supplementary XAS calculation)"},{"comment":"The abstract promises that the paper includes and discusses 'Jahn-Teller (JT) distortions,' and the introduction similarly says 'we discuss the role of the JT effect in Mn3+ ions,' but no JT term appears in the Hamiltonian H of Eq. (1) or anywhere in the main text or the supplementary material. The only structural ingredient is a static cubic crystal field 10Dq. Either add a JT calculation (for example, symmetry-lowering distortions of the eg orbitals) or remove all JT statements; as written, the abstract misrepresents the content of the paper.","section":"Abstract and 'ANDERSON IMPURITY MODEL' (Eq. (1))"},{"comment":"The quantitative claim that the AIM 'successfully mirrors experimental results' is weakened by the fact that the model parameters are explicitly adjusted to fit the same experimental spectra that are then reproduced, and the experimental spectra are presented without error bars or a goodness-of-fit metric. The r/s scan does isolate the effect of CT and CVEC, and this part is not circular, but it does not validate the absolute parameter set. Please include a sensitivity analysis (for example, varying Udd, Delta, 10Dq, and h within realistic ranges) and compare with experimental uncertainties; at minimum, the text should state clearly that the agreement is a constrained fit rather than an ab initio prediction.","section":"'ANDERSON IMPURITY MODEL' and Table I; supplementary Fig. S2"},{"comment":"The single-site AIM with five ligand orbitals and a static mean-field magnetic field mu_B h = 0.01 eV is a strong approximation for a metallic ferromagnet, and the authors themselves note that the AIM density of states only qualitatively captures the DFT result and that metallic bands at the Fermi level differ due to finite-size cluster limits. Because the 644.6 eV feature is assigned to CVEC-driven transitions in the intermediate state, the paper should demonstrate that this assignment is robust to (i) the number and energy distribution of the ligand orbitals, (ii) the value of h, and (iii) the inclusion of band-like continua. A concrete test would be to vary the bath representation while keeping the local multiplet parameters fixed and to show that the sign and position of the CVEC-induced subpeak survive.","section":"Supplementary Materials, Fig. S2 and 'ANDERSON IMPURITY MODEL'"}],"minor_comments":[{"comment":"The sentence 'the XAS spectra of LSMO are measured with two orthogonal polarizations: right circular polarization (RCP) and left circular polarization (LCP)' is correct, but the parenthetical 'with RCP (µ+) and LCP (µ+)' contains a typo: the second polarization label should read µ−.","section":"EXPERIMENTAL RESUL TS"},{"comment":"There are typos in the text: '644.6 eV eV' should be '644.6 eV', and 'ranging form d4L1' should be 'ranging from d4L1'; in the RIXS-MCD section, 'RIXS-XMCD' should be 'RIXS-MCD' for consistency.","section":"XMCD SPECTRA"},{"comment":"The definitions of the Slater parameters and the charge-transfer energy should be given with explicit sign conventions; in particular, the relation Delta = E(d4L1) - E(d3) = 3Udd + 6Upd - epsL assumes a specific choice of ligand-hole energy, and the sign of epsL relative to the chemical potential should be stated.","section":"ANDERSON IMPURITY MODEL"},{"comment":"The RIXS and RIXS-MCD maps are shown without a color scale, so the magnitude of the dichroic signal cannot be assessed from the figures; please add a common color bar or state the intensity normalization.","section":"Figures 1 and 4"},{"comment":"The notation for configurations such as t^3_{2g up} e^1_{g up} L^1_{eg up} is difficult to follow in the printed text; a consistent typesetting convention with explicit subscripts for ligand orbitals would improve readability.","section":"RIXS-MCD SPECTRA"}],"recommendation":"major_revision","confidential_remarks":"The core spectral-shape analysis is defensible and the r/s scan is a nice way to separate the contributions of CT and CVEC. The main obstacle to publication is the unsupported sum-rule claim, which is the headline message. I would ask the authors to either prove the sum-rule failure within their own model or substantially soften the conclusion. The JT mismatch between the abstract and the actual content is also an editorial issue that should be fixed before resubmission. The paper is within the scope of the journal and, after these revisions, should be publishable."},"author_rebuttal":null,"desk_editor":{"model":"deepseek-v4-flash","letter":"Colleague,\n\nPunchline: this is the first calculation I've seen showing that full charge transfer beyond d^(n+1)L and core-valence exchange correlation are both needed to reproduce the XMCD subpeak structure of LSMO. That is a real step forward, and the new TES-based RIXS-MCD map is a nice piece of data. Worth a serious referee.\n\nWhat it does well: the r/s scaling cleanly isolates CT from CVEC, the PED analysis identifies which configurations contribute to which subpeaks, and the comparison with the conventional weighted-sum approach shows the old method fails on the 644.6 eV feature. The paper earns its central structural claim: s=1 flips the L3 subpeak sign, and that explains the experiment.\n\nSoft spots, in order of importance. First, the sum-rule argument. The paper states that the anomalous subpeak sign means \"the conventional analysis on the XMCD sign, hence the sum-rule, is no longer valid.\" That does not follow. Sum rules are integrals over the L2/L3 edges, not pointwise sign statements. The authors never integrate their own computed s=0 and s=1 spectra and compare with the ground-state L_z, S_z, T_z expectations. That is a load-bearing gap: the practical \"profound impact\" message depends on it. They should do that calculation; it is cheap. Second, the abstract promises Jahn-Teller distortions, but the main text never mentions them in the calculations. Either add the JT term or drop it from the abstract. Third, the model parameters are adjusted to fit the spectra being explained. That is normal in this field, but the paper should be more explicit about overfitting risk, and a parameter sensitivity test (e.g., on Udd, Delta) would strengthen it. No error bars on the experimental data, no code or data release—a transparency problem, not a scientific one.\n\nThe single-site AIM with five bath orbitals is a simplification for a metallic ferromagnet, but the qualitative DFT DOS comparison in the supplement shows it captures the relevant features on the 10 eV scale. That assumption is defensible.\n\nWho it is for: X-ray spectroscopists and people who do sum-rule extractions on 3d oxides. They should read it carefully. I would cite it for the RIXS-MCD map and the full-CT demonstration, but not for the sum-rule invalidation until the direct test appears.\n\nRecommendation: send to peer review. The central spectral-shape result is solid and reproducible in principle. The referee should ask for the sum-rule check and the JT fix, but neither should sink the paper.","headline":"Solid spectroscopy paper with a genuinely new full-CT+CVEC result, but the sum-rule invalidation claim needs a direct test before it can carry the weight the authors put on it.","tokens_in":22836,"tokens_out":2048,"would_cite":true,"duration_ms":27703,"reading_group":"yes","serious_thinker":"yes","would_accept_peer_review":true},"rs_alignment":null,"lean_confirmation":null,"pith_extraction":{"msc":[],"pacs":[],"model":"deepseek-v4-flash","headline":"A single-site Anderson impurity model that includes the full charge-transfer series and core-valence exchange correlation reproduces the XMCD and RIXS-MCD spectra of La0.7Sr0.3MnO3, and shows that standard sum-rule spin and orbital…","keywords":["X-ray magnetic circular dichroism","resonant inelastic X-ray scattering","Anderson impurity model","charge transfer","core-valence exchange correlation","mixed-valence manganites","XMCD sum rules","La0.7Sr0.3MnO3"],"falsifier":"A calculation with the same core-valence exchange parameters but with charge transfer truncated at the lowest $d^{n+1}L^1$ configuration that still reproduces the 644.6 eV L3 subpeak and the same-sign L2 feature would falsify the claim that full charge transfer is required; alternatively, comparing sum-rule-derived spin and orbital moments from these spectra with magnetometry or polarized neutron data on the same film would reveal whether the predicted systematic errors are real.","tokens_in":2085,"feed_emoji":"🧲","tokens_out":3845,"duration_ms":111500,"temperature":0.7,"pith_summary":"This paper seeks to explain the complete measured X-ray magnetic circular dichroism (XMCD) and resonant inelastic X-ray scattering (RIXS-MCD) spectra of the mixed-valence ferromagnet La0.7Sr0.3MnO3, including the secondary peaks that conventional calculations miss. The authors argue that a single-site Anderson impurity model must include the entire charge-transfer series, from configurations $d^3L^0$ to $d^{10}L^7$, together with many-body core-valence exchange correlation (CVEC) between the Mn 2p core and 3d valence electrons. With both ingredients, the calculation reproduces the experimental dichroism subpeaks; without them, the weighted-sum approach used for mixed-valence ions does not. If correct, the result implies that the widely used XMCD sum rules systematically misestimate spin and orbital moments in light 3d mixed-valence systems, because CVEC redistributes spectral weight across the L3 and L2 edges.","feed_headline":"One impurity model reproduces manganite X-ray dichroism spectra","feed_subtitle":"A full charge-transfer model captures the subpeaks that standard mixed-valence sums miss, exposing sum-rule bias.","key_machinery":"The carrying object is the Anderson impurity model Hamiltonian $H = H_d + H_c + H_{dc} + H_L + H_t$, composed of Mn 3d and 2p ionic terms with cubic crystal field, spin-orbit coupling, an exchange field of $\\mu_B h = 0.01$ eV, Slater-Condon Coulomb integrals, and five identical ligand (bath) orbitals coupled by $\\sigma$-type and pi-type hoppings. Full charge transfer means the Hilbert space contains all configurations from $d^3L^0$ to $d^{10}L^7$, not just the lowest $d^{n+1}L^1$ state, so the ground state becomes an admixture of roughly 30% $d^3L^0$, 49% $d^4L^1$, and 19% $d^5L^2$ configurations that reflects LSMO's valence fluctuations. Core-valence exchange correlation (CVEC) is the set of multipole Coulomb interactions between the 2p core hole and 3d valence electrons; it is inert in the ground and final states but restructures the intermediate states of XAS and RIXS, and the paper identifies which final multiplet configurations carry each dichroic peak using partial excitation densities.","core_discovery":"The central discovery is that the experimentally observed XMCD subpeak near 644.6 eV and the same-sign dichroism at the L2 edge do not originate from independent Mn3+ and Mn4+ ions combined in a fixed ratio. They emerge only when the Anderson impurity model allows dynamic charge fluctuations across the full configuration space $d^3L^0$ through $d^{10}L^7$ and includes the Slater-Condon core-valence exchange interactions $F_{pd}^2$, $G_{pd}^1$, and $G_{pd}^3$. Without CVEC, the L3 subpeak has the wrong sign and the distinctive positive L2 feature is absent, and the simple one-electron dipole picture of core-to-valence transitions remains adequate; with CVEC, intermediate-state multiplets mix p1/2 and p3/2 core holes with valence d excitations, changing the dichroic line shapes and breaking the assumptions behind the conventional sum rules.","pith_inferences":["Beyond the paper's explicit claims, the CVEC-induced failure of sum rules likely extends to other light 3d mixed-valence oxides with published XMCD moments; a clean test would compare sum-rule-derived moments with magnetometry or polarized neutron data on the same films.","The paper's mechanism suggests that DFT- or DMFT-derived one-particle parameters fed into the same impurity model should produce quantitative band effects, a route the authors themselves identify as future work.","Because the fitted ground state contains a nontrivial 19% $d^5L^2$ weight, higher-order charge-transfer states may be generically important in metallic manganites; a natural extension is to test whether the 644.6 eV feature shifts or splits when the ligand bath is enlarged beyond five orbitals.","One could make a predictive extension by applying the same full-CT/CVEC calculation to other doping levels of La1-xSrxMnO3 and checking whether the separation of the two XMCD subpeaks scales with doping as the model parameters imply."],"forward_implications":["XMCD sum-rule spin and orbital moments extracted from L2,3 edges of mixed-valence 3d oxides can be systematically wrong; the same-sign subpeaks and overshoot cannot be interpreted with one-electron dipole transitions.","Conventional weighted sums of Mn3+ and Mn4+ spectra, even when one charge-transfer state ($d^4L^1$ or $d^5L^1$) is included, cannot reproduce the LSMO XMCD, so full charge transfer is necessary.","RIXS-MCD maps depend strongly on incident photon energy, and CVEC splits the intermediate states, so the signs and selection rules in RIXS-MCD cannot be read off from the XMCD alone.","The recorded dd-excitation dichroic signal near 644.6 eV is tied to CVEC-modified intermediate states, making RIXS-MCD an element-specific route to orbital and charge excitations in correlated metals.","The same full-CT/CVEC treatment is positioned as the practical interpretive model for dichroic x-ray spectroscopies in other mixed-valence transition-metal oxides."],"supporting_citations":[{"why":"Establishes magnetic x-ray dichroism as the experimental probe the paper's model reproduces.","marker":"[15]"},{"why":"Provides the XMCD sum-rule confirmation for Fe and Co that the paper argues does not carry over to mixed-valence 3d systems.","marker":"[17]"},{"why":"States the orbital-moment sum rule used in standard XMCD analysis.","marker":"[18]"},{"why":"States the spin sum rule and local-field version that CVEC is shown to break.","marker":"[19]"},{"why":"Supplies the RIXS Kramers-Heisenberg formalism and classification of elementary excitations used for the RIXS-MCD maps.","marker":"[21]"},{"why":"Documents the diffused-moment overshoot behavior in XMCD that the paper connects to sum-rule over- and underestimation.","marker":"[28]"},{"why":"Describes the conventional multiplet configuration-interaction approach that limits charge transfer to a single $d^{n+1}L^1$ state and serves as the contrast for the full-CT treatment.","marker":"[35]"},{"why":"Provides the conventional configuration-interaction software used to generate the Mn3+/Mn4+ weighted-sum XMCD baselines that fail to match experiment.","marker":"[36]"},{"why":"Gives the exact-diagonalization solver used to obtain the AIM ground state and spectra.","marker":"[38]"},{"why":"Quantifies the accuracy limit of the spin sum rule at transition-metal L edges, supporting the paper's caution about extracted moments.","marker":"[44]"}],"fun_headline_variants":["Charge transfer and core-valence exchange explain XMCD subpeaks","Dynamic charge fluctuations fix X-ray dichroism sum-rule bias","Full CT model captures dichroic subpeaks missing in simple sums","Many-body correlations reshape manganite X-ray spectra","CVEC and CT unlock manganite dichroism interpretation"],"cache_read_input_tokens":24832,"weakest_assumption_plain":"The argument leans on a single-site Anderson impurity model with five ligand orbitals and a static mean-field exchange field ($\\mu_B h = 0.01$ eV) standing in for the metallic, band-like LSMO film over the roughly 10 eV window of the Mn L2,3 edges; the paper itself concedes that its density of states only qualitatively matches band structure near the Fermi level.","fun_headline_variants_meta":{"raw":{"variants":["Charge transfer and core-valence exchange explain XMCD subpeaks","Dynamic charge fluctuations fix X-ray dichroism sum-rule bias","Full CT model captures dichroic subpeaks missing in simple sums","Many-body correlations reshape manganite X-ray spectra","CVEC and CT unlock manganite dichroism interpretation"]},"model":"deepseek-v4-flash","effort":"low","cost_usd":0.0002,"raw_usage":{"total_tokens":1392,"prompt_tokens":978,"completion_tokens":414,"prompt_tokens_details":{"cached_tokens":384},"prompt_cache_hit_tokens":384,"prompt_cache_miss_tokens":594,"completion_tokens_details":{"reasoning_tokens":325}},"tokens_in":594,"tokens_out":414,"duration_ms":4488,"temperature":1.0,"reasoning_tokens":325,"cache_read_input_tokens":384,"cache_creation_input_tokens":0},"cache_creation_input_tokens":0},"created_at":"2026-08-11T18:59:12.981767+00:00","model_set":{"reader":"deepseek-v4-flash"},"falsifier":"A calculation with the same core-valence exchange parameters but with charge transfer truncated at the lowest $d^{n+1}L^1$ configuration that still reproduces the 644.6 eV L3 subpeak and the same-sign L2 feature would falsify the claim that full charge transfer is required; alternatively, comparing sum-rule-derived spin and orbital moments from these spectra with magnetometry or polarized neutron data on the same film would reveal whether the predicted systematic errors are real.","supporting_citations":[{"cited_title":"van der Laan, B","cited_arxiv_id":null,"evidence_quote":"Establishes magnetic x-ray dichroism as the experimental probe the paper's model reproduces."},{"cited_title":null,"cited_arxiv_id":null,"evidence_quote":"Provides the XMCD sum-rule confirmation for Fe and Co that the paper argues does not carry over to mixed-valence 3d systems."},{"cited_title":"Carra, B","cited_arxiv_id":null,"evidence_quote":"States the spin sum rule and local-field version that CVEC is shown to break."},{"cited_title":null,"cited_arxiv_id":null,"evidence_quote":"Supplies the RIXS Kramers-Heisenberg formalism and classification of elementary excitations used for the RIXS-MCD maps."},{"cited_title":null,"cited_arxiv_id":null,"evidence_quote":"Documents the diffused-moment overshoot behavior in XMCD that the paper connects to sum-rule over- and underestimation."},{"cited_title":"de Groot, Multiplet effects in X-ray spectroscopy, Co- ord","cited_arxiv_id":null,"evidence_quote":"Describes the conventional multiplet configuration-interaction approach that limits charge transfer to a single $d^{n+1}L^1$ state and serves as the contrast for the full-CT treatment."},{"cited_title":"Stavitski and F","cited_arxiv_id":null,"evidence_quote":"Provides the conventional configuration-interaction software used to generate the Mn3+/Mn4+ weighted-sum XMCD baselines that fail to match experiment."},{"cited_title":"Wu and H","cited_arxiv_id":null,"evidence_quote":"Gives the exact-diagonalization solver used to obtain the AIM ground state and spectra."},{"cited_title":"Piamonteze, P","cited_arxiv_id":null,"evidence_quote":"Quantifies the accuracy limit of the spin sum rule at transition-metal L edges, supporting the paper's caution about extracted moments."}],"review_version":1}