Increasing the lattice constant shifts TCNQ adsorbate-adsorbate interactions from repulsive to attractive, favoring tight-packing polymorphs and inducing a lattice-constant-driven phase transition.
Assembly of 2D ionic layers by reaction of alkali halides with the organic electrophile 7,7,8,8-tetracyano-p-quinodimethane (TCNQ)
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Impact of the Lattice Constant on the Polymorphism of Organic/Inorganic Interfaces
Increasing the lattice constant shifts TCNQ adsorbate-adsorbate interactions from repulsive to attractive, favoring tight-packing polymorphs and inducing a lattice-constant-driven phase transition.