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arxiv: 0710.3310 · v1 · submitted 2007-10-17 · ❄️ cond-mat.soft · cond-mat.stat-mech

Two-parameter model predictions and theta-point crossover for linear-polymer solutions

classification ❄️ cond-mat.soft cond-mat.stat-mech
keywords crossovermodelosmoticpolymerpressureradiustheta-pointtwo-parameter
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We consider the first few virial coefficients of the osmotic pressure, the radius of gyration, the hydrodynamic radius, and the end-to-end distance for a monodisperse polymer solution. We determine the corresponding two-parameter model functions which parametrize the crossover between the good-solvent and the ideal-chain behavior. These results allow us to predict the osmotic pressure and the polymer size in the dilute regime in a large temperature region above the theta-point.

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