Engineering molecular aggregate spectra
classification
❄️ cond-mat.mtrl-sci
cond-mat.dis-nn
keywords
aggregatesmolecularsurfaceabsorptionaggregatearrangementbandchanges
read the original abstract
We show that optical properties of linear molecular aggregates undergo drastic changes when aggregates are deposited on a metal surface. The dipole-dipole interactions of monomers with their images can result in strong {re-structuring of both the exciton band and the absorption spectrum, depending on the arrangement of the monomer transition dipoles with respect to the surface.
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