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arxiv: 0809.5239 · v1 · submitted 2008-09-30 · ❄️ cond-mat.soft

Screening of hydrodynamic interactions for polyelectrolytes in salt solution

classification ❄️ cond-mat.soft
keywords hydrodynamicsaltexplicitinteractionspolyelectrolytessolutiontimeanalytical
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We provide numerical evidence that hydrodynamic interactions are screened for charged polymers in salt solution on time scales below the Zimm time. At very short times, a crossover to hydrodynamic behavior is observed. Our conclusions are drawn from extensive coarse-grained computer simulations of polyelectrolytes in explicit solvent and explicit salt, and discussed in terms of analytical arguments based on the Debye-Hueckel approximation.

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