Magnetic anomalies in Gd6Co1.67Si3 and Tb6Co1.67Si3

The compounds, Gd6Co1.67Si3 and Tb6Co1.67Si3, recently reported to form in a Ce6Ni2Si3-derived hexagonal structure (space group: P6_3 / m) and to order magnetically below 295 and 190 K respectively, have been investigated by detailed magnetization (M) studies in the temperature interval 1.8-330 K as a function of magnetic field (H). The points of emphasis are: We observe multiple steps in the M(H) curve for the Tb compound at 1.8 K while increasing H, but these steps do not appear in the reverse cycle of H. At higher temperatures, such steps are absent. However, this 'staircase' behavior of M(H) is not observed for the Gd compound at any temperature and the isothermal magnetization is not hysteretic unlike in Tb compound. From the M(H) data measured at close intervals of temperature, we have derived isothermal entropy change (Delta S) and it is found that Delta S follows a theoretically predicted H^2/3-dependence.