Spin amplitude modulation driven magnetoelectic coupling in the new multiferroic FeTe₂O₅Br

Magnetic and ferroelectric properties of layered geometrically frustrated cluster compound FeTe$_2$O$_5$Br were investigated with single-crystal neutron diffraction and dielectric measurements. Incommensurate amplitude modulated magnetic order with the wave vector $\bf{q}$=($\half$, 0.463, 0) develops below $T_N=10.6(2) {\rm K}$. Simultaneously, a ferroelectric order with the spontaneous polarization perpendicular to ${\bf q}$ and to Fe$^{3+}$ magnetic moments emerges. The observed ferroelectricity and extraordinary linear scaling of the ferroelectric and magnetic order parameter are provoked by the striction of the intercluster Fe-O-Te-O-Fe bridges leading to the shift of Te$^{4+}$ ions and polarization of their lone-pair electrons.