Large spin relaxation rates in trapped submerged-shell atoms

Spin relaxation due to atom-atom collisions is measured for magnetically trapped erbium and thulium atoms at a temperature near 500 mK. The rate constants for Er-Er and Tm-Tm collisions are 3.0 times 10^-10 cm^3 s^-1 and 1.1 times 10^-10 cm^3 s^-1, respectively, 2-3 orders of magnitude larger than those observed for highly magnetic S-state atoms. This is strong evidence for an additional, dominant, spin relaxation mechanism, electrostatic anisotropy, in collisions between these "submerged-shell" L > 0 atoms. These large spin relaxation rates imply that evaporative cooling of these atoms in a magnetic trap will be highly inefficient.