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arxiv: 1004.5259 · v1 · submitted 2010-04-29 · ⚛️ physics.atom-ph · math-ph· math.MP

Coupled tensorial form for atomic relativistic two-particle operator given in second quantization representation

classification ⚛️ physics.atom-ph math-phmath.MP
keywords coupledoperatorformtensorialatomicgivenquantizationrelativistic
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General formulas of the two-electron operator representing either atomic or effective interactions are given in a coupled tensorial form in relativistic approximation. The alternatives of using uncoupled, coupled and antisymmetric two-electron wave functions in constructing coupled tensorial form of the operator are studied. The second quantization technique is used. The considered operator acts in the space of states of open-subshell atoms.

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