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arxiv: 1710.01975 · v1 · pith:2QEJUJAJnew · submitted 2017-10-05 · ❄️ cond-mat.soft · physics.flu-dyn

Velocity gradient power functional for Brownian dynamics

classification ❄️ cond-mat.soft physics.flu-dyn
keywords functionalbrowniandynamicsgradientpowersuperadiabaticvelocityaccuracy
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We present an explicit and simple approximation for the superadiabatic excess (over ideal gas) free power functional, admitting the study of the nonequilibrium dynamics of overdamped Brownian many-body systems. The functional depends on the local velocity gradient and is systematically obtained from treating the microscopic stress distribution as a conjugate field. The resulting superadiabatic forces are beyond dynamical density functional theory and are of viscous nature. Their high accuracy is demonstrated by comparison to simulation results.

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