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arxiv: cond-mat/0012256 · v1 · submitted 2000-12-14 · ❄️ cond-mat.soft · cond-mat.stat-mech

What do emulsification failure and Bose-Einstein condensation have in common?

classification ❄️ cond-mat.soft cond-mat.stat-mech
keywords bose-einsteincondensationoccursringemulsificationfailurephasepolymers
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Ideal bosons and classical ring polymers formed via self-assembly, are known to have the same partition function, and so analogous phase transitions. In ring polymers, the analogue of Bose-Einstein condensation occurs when a ring polymer of macroscopic size appears. We show that a transition of the same general form occurs within a whole class of systems with self-assembly, and illustrate it with the emulsification failure of a microemulsion phase of water, oil and surfactant. As with Bose-Einstein condensation, the transition occurs even in the absence of interactions.

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