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arxiv: 0811.2140 · v3 · submitted 2008-11-13 · 🪐 quant-ph · physics.atm-clus

Hund's paradox and the collisional stabilization of chiral molecules

classification 🪐 quant-ph physics.atm-clus
keywords collisionalmoleculeschiralconfigurationallowscomparedconditionscoupled-channel
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We identify the dominant collisional decoherence mechanism which serves to stabilize and super-select the configuration states of chiral molecules. A high-energy description of this effect is compared to the results of the exact molecular scattering problem, obtained by solving the coupled-channel equations. It allows to predict the experimental conditions for observing the collisional suppression of the tunneling dynamics between the left-handed and the right-handed configuration of D2S2 molecules.

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