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arxiv: 1110.3932 · v3 · pith:6RBODPSNnew · submitted 2011-10-18 · ⚛️ physics.chem-ph · physics.atom-ph· quant-ph

Optical Activity, Hund Paradox, and Molecular Parity Violation

classification ⚛️ physics.chem-ph physics.atom-phquant-ph
keywords activityhundmolecularopticalparadoxparitypotentialviolation
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We study the problem of stability of optical activity, also known as Hund paradox, in a two-dimensional approximation of a double-well potential. We discuss how the introduction of molecular parity violation breaks the symmetry of the potential. By using a dynamical approach, we show how this effect modifies the dynamics and can stabilize the chiral states for some molecules.

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