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arxiv: 1202.1092 · v1 · pith:ULX7MAXNnew · submitted 2012-02-06 · ⚛️ physics.chem-ph · cond-mat.other· cond-mat.str-el

Uniform electron gases

classification ⚛️ physics.chem-ph cond-mat.othercond-mat.str-el
keywords densityelectronfiniteinfiniteparameteruniformacrossargue
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We show that the traditional concept of the uniform electron gas (UEG) --- a homogeneous system of finite density, consisting of an infinite number of electrons in an infinite volume --- is inadequate to model the UEGs that arise in finite systems. We argue that, in general, a UEG is characterized by at least two parameters, \textit{viz.} the usual one-electron density parameter $\rho$ and a new two-electron parameter $\eta$. We outline a systematic strategy to determine a new density functional $E(\rho,\eta)$ across the spectrum of possible $\rho$ and $\eta$ values.

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